The fact that at this stage the polarization is a maximum, when the angle through which the light is turned exceeds a right angle, is the more worthy of note, as the opposite result would prob ably have been expected. By Brewster's law this angle in the case of regular reflection from a plate is less than a right angle; so that not only is the law of polarization for a very small par tide different from that applicable to a plate, but the first effect of an increase of size is to augment the difference.
To illustrate further the complications that arise when the particle3 are not infinitely small it may be mentioned that if the solution of "hypo" prepared as above be observed for a longer time it becomes more opaque owing to the growth of the sulphur particles and afterwards becomes more transparent again even though kept well stirred ; and further that in this last stage it transmits blue more than red and consequently scatters red more than blue. This is a complete reversal of the blue-sky effect. (Keen and Porter, Roy. Soc. Proc. A. 1914.) A similar phenomenon had previously been observed by Captain Abney and by W. Ritz. Abney says in connection with certain suspensions of silver bromide in collodion: "In some cases I obtained it in such a state which, when viewed by transmitted light, appeared of a sky-blue colour inclining to green." (Abney, Phil. Trans. Roy. Soc. Pt. II., p. 653, 188o W. Ritz, Comptes Rendus 167, 1906.) This phenomenon is well known to preparers of emulsions for photographic plates.
Related to abnormalities of colour we may expect to find cor responding abnormalities in polarization. Of this nature are the neutral points, where the polarization changes character, ob served by F. J. D. Arago, J. Babinet and Sir D. Brewster for an account of which reference may be made to Mascart, Traite d'Optique• (R. ; A. W. Po.)